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Issue 4, 2003
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Micellar media for the efficient ring opening of epoxides with CN, N3, NO3, NO2, SCN, Cl and Br catalyzed with Ce(OTf)4

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Abstract

Micellar media are introduced for the efficient ring opening of epoxides with sodium salts of nucleophiles such as CN, N3, NO3, NO2, SCN, Br and Cl, catalyzed with Ce(OTf)4. This method is an efficient procedure for the synthesis of different β-substituted alcohols under mild reaction conditions. The reaction with SCN is an easy procedure for the high yielding preparation of epoxy sulfides.

Graphical abstract: Micellar media for the efficient ring opening of epoxides with CN−, N3−, NO3−, NO2−, SCN−, Cl− and Br− catalyzed with Ce(OTf)4

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Publication details

The article was received on 27 Nov 2002, accepted on 09 Jan 2003 and first published on 28 Jan 2003


Article type: Paper
DOI: 10.1039/B211697A
Org. Biomol. Chem., 2003,1, 724-727

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    Micellar media for the efficient ring opening of epoxides with CN, N3, NO3, NO2, SCN, Cl and Br catalyzed with Ce(OTf)4

    N. Iranpoor, H. Firouzabadi and M. Shekarize, Org. Biomol. Chem., 2003, 1, 724
    DOI: 10.1039/B211697A

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