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Issue 3, 2003
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First synthesis of 2′,3′-epimino-carbocyclic nucleosides

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Abstract

The preparation of 2′,3′-epimino-carbocyclic analogues of adenosine is reported. The reaction of p-tosyl azide with N-substituted 2-azabicyclo[2.2.1]hept-5-en-3-one (ABH) (1a) provided aziridine-fused ABH (2), which was converted to 2′,3′-epimino-carbocyclic nucleosides (11).

Graphical abstract: First synthesis of 2′,3′-epimino-carbocyclic nucleosides

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Article information


Submitted
07 Nov 2002
Accepted
16 Dec 2002
First published
07 Jan 2003

Org. Biomol. Chem., 2003,1, 452-453
Article type
Communication

First synthesis of 2′,3′-epimino-carbocyclic nucleosides

M. Ishikura, A. Murakami and N. Katagiri, Org. Biomol. Chem., 2003, 1, 452
DOI: 10.1039/B210963H

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