We report the first synthesis of poly(triacetylene)-derived oligomers by Pd(0)-catalysed Sonogashira and Cadiot–Chodkiewicz-type cross-coupling reactions on solid support. Oligo(phenylene triacetylene)s, members of a new class of linearly π-conjugated oligomers with all-carbon backbones, feature very high fluorescence intensities.
N. F. Utesch and F. Diederich, Org. Biomol. Chem., 2003, 1, 237 DOI: 10.1039/B210184J
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