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Issue 34, 2019
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High-quality graphene transfer via directional etching of metal substrates

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Abstract

Large-scale applications of graphene require its high-efficiency transfer from growth metal substrates to any other substrates of interest. The wrinkles and folds generated during the transfer process of graphene by the well-known poly(methyl methacrylate) (PMMA)-assisted technique is a critical issue. Here, we report an improvement of this method by applying a directional etching process for the removal of the growth Cu substrates, using a pair of electrodes inserted into the etchant with a constant current to form an electrochemical system. The controlled redox reactions between the Cu and the solution environment result in the etching of Cu in a part-by-part manner strictly from one end to the other. The consistency of the Cu etching direction can avoid the formation of an easily destroyable Cu structure and release the stress concentration that is usually generated during the random etching process, and finally yield significantly improved quality of the transferred graphene film with a lowered density of wrinkles, cracks/folds, adlayers, reduced root-mean-square of surface roughness, and increased performance in sheet resistance and carrier mobility.

Graphical abstract: High-quality graphene transfer via directional etching of metal substrates

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Publication details

The article was received on 23 Jun 2019, accepted on 12 Aug 2019 and first published on 13 Aug 2019


Article type: Paper
DOI: 10.1039/C9NR05315H
Nanoscale, 2019,11, 16001-16006

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    High-quality graphene transfer via directional etching of metal substrates

    X. Zhang, Z. Wu, H. Zheng, Q. Ren, Z. Zou, L. Mei, Z. Zhang, Y. Xia, C. Lin, P. Zhao and H. Wang, Nanoscale, 2019, 11, 16001
    DOI: 10.1039/C9NR05315H

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