Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 22nd May 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 45, 2018
Previous Article Next Article

Switchable synchronisation of pirouetting motions in a redox-active [3]rotaxane

Author affiliations

Abstract

In this study, the crown/ammonium [3]rotaxane R2 is reported which allows a switchable synchronisation of wheel pirouetting motions. The rotaxane is composed of a dumbbell-shaped axle molecule with two mechanically interlocked macrocycles which are decorated with a redox-active tetrathiafulvalene (TTF) unit. Electrochemical, spectroscopic, and electron paramagnetic resonance experiments reveal that rotaxane R2 can be reversibly switched between four stable oxidation states (R2, R2˙+, R22(˙+), and R24+). The oxidations enable non-covalent, cofacial interactions between the TTF units in each state—including a stabilised mixed-valence (TTF2+ and a radical-cation (TTF˙+)2 dimer interaction—which dictate a syn (R2, R2˙+, and R22(˙+)) or anti (R24+) ground state co-conformation of the wheels in the rotaxane. Furthermore, the strength of these wheel–wheel interactions varies with the oxidation state, and thus electrochemical switching allows a controllable synchronisation of the wheels’ pirouetting motions. DFT calculations explore the potential energy surface of the counter-rotation of the two interacting wheels in all oxidation states. The controlled coupling of pirouetting motions in rotaxanes can lead to novel molecular gearing systems which transmit rotational motion by switchable non-covalent interactions.

Graphical abstract: Switchable synchronisation of pirouetting motions in a redox-active [3]rotaxane

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Jul 2018, accepted on 23 Oct 2018 and first published on 24 Oct 2018


Article type: Paper
DOI: 10.1039/C8NR05534C
Nanoscale, 2018,10, 21425-21433

  •   Request permissions

    Switchable synchronisation of pirouetting motions in a redox-active [3]rotaxane

    H. V. Schröder, A. Mekic, H. Hupatz, S. Sobottka, F. Witte, L. H. Urner, M. Gaedke, K. Pagel, B. Sarkar, B. Paulus and C. A. Schalley, Nanoscale, 2018, 10, 21425
    DOI: 10.1039/C8NR05534C

Search articles by author

Spotlight

Advertisements