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Issue 1, 2017

Macroscopic and tunable nanoparticle superlattices

Author affiliations

Abstract

We describe a robust method to assemble nanoparticles into highly ordered superlattices by inducing aqueous phase separation of neutral capping polymers. Here we demonstrate the approach with thiolated polyethylene-glycol-functionalized gold nanoparticles (PEG-AuNPs) in the presence of salts (for example, K2CO3) in solutions that spontaneously migrate to the liquid–vapor interface to form a Gibbs monolayer. We show that by increasing salt concentration, PEG-AuNP monolayers transform from two-dimensional (2D) gas-like to liquid-like phase and eventually, beyond a threshold concentration, to a highly ordered hexagonal structure, as characterized by surface sensitive synchrotron X-ray reflectivity and grazing incidence X-ray diffraction. Furthermore, the method allows control of the inplane packing in the crystalline phase by varying the K2CO3 and PEG-AuNPs concentrations and the length of PEG. Using polymer-brush theory, we argue that the assembly and crystallization is driven by the need to reduce surface tension between PEG and the salt solution. Our approach of taking advantage of the phase separation of PEG in salt solutions is general (i.e., can be used with any nanoparticles) leads to high-quality macroscopic and tunable crystals. Finally, we discuss how the method can also be applied to the design of orderly 3D structures.

Graphical abstract: Macroscopic and tunable nanoparticle superlattices

Supplementary files

Article information


Submitted
08 Sep 2016
Accepted
21 Oct 2016
First published
24 Oct 2016

Nanoscale, 2017,9, 164-171
Article type
Paper

Macroscopic and tunable nanoparticle superlattices

H. Zhang, W. Wang, S. Mallapragada, A. Travesset and D. Vaknin, Nanoscale, 2017, 9, 164 DOI: 10.1039/C6NR07136H

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