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Issue 23, 2016
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Novel CoS2 embedded carbon nanocages by direct sulfurizing metal–organic frameworks for dye-sensitized solar cells

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Abstract

Owing to its excellent electrocatalytic properties, cobalt disulfide (CoS2) is regarded as a promising counter electrode (CE) material for dye-sensitized solar cells (DSSCs). However, hindered by its relatively poor electrical conductivity and chemical instability, it remains a challenge to apply it into high-performance DSSCs. In this work, we have developed novel CoS2 embedded carbon nanocages as a CE in DSSCs, using ZIF-67 (zeolitic imidazolate framework 67, Co(mim)2, mim = 2-methylimidolate) as a template. The CoS2 samples sulfurized for different time lengths are prepared through a facile solution process. It is found that the sulfurization time can be optimized to maximize the DSSC efficiency and the DSSC based on the CoS2 embedded carbon nanocages sulfurized for 4 hours exhibits the highest photovoltaic conversion efficiency (PCE) of 8.20%, higher than those of DSSCs consisting of other CoS2 CEs and Pt-based DSSC (7.88%). The significantly improved DSSC PCE is contributed by the synergic effect of inner CoS2 nanoparticles and an amorphous carbon matrix, leading to a CE with high catalytic activity, good electrical conductivity and excellent durability. This study demonstrates that the CE based on inexpensive CoS2 embedded carbon nanocages is a prospective substitute to expensive platinum and provides a new approach for commercializing high-efficiency DSSCs.

Graphical abstract: Novel CoS2 embedded carbon nanocages by direct sulfurizing metal–organic frameworks for dye-sensitized solar cells

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Publication details

The article was received on 13 Apr 2016, accepted on 22 May 2016 and first published on 23 May 2016


Article type: Paper
DOI: 10.1039/C6NR03052A
Nanoscale, 2016,8, 11984-11992

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    Novel CoS2 embedded carbon nanocages by direct sulfurizing metal–organic frameworks for dye-sensitized solar cells

    X. Cui, Z. Xie and Y. Wang, Nanoscale, 2016, 8, 11984
    DOI: 10.1039/C6NR03052A

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