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Issue 42, 2015
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Catalytic effect of ultrananocrystalline Fe3O4 on algal bio-crude production via HTL process

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We report a comprehensive quantitative study of the production of refined bio-crudes via a controlled hydrothermal liquefaction (HTL) process using Ulva fasciata macroalgae (UFMA) as biomass and ultrananocrystalline Fe3O4 (UNCFO) as catalyst. X-ray diffraction and electron microscopy were applied to elucidate the formation of the high-quality nanocatalysts. Gas chromatography-mass spectroscopy (GC-MS) and CHNS analyses showed that the bio-crude yield and carbon/oxygen ratios increase as the amount of UNCFO increases, reaching a peak value of 32% at 1.25 wt% (a 9% increase when compared to the catalyst-free yield). The bio-crude is mainly composed of fatty acids, alcohols, ketones, phenol and benzene derivatives, and hydrocarbons. Their relative abundance changes as a function of catalyst concentration. FTIR spectroscopy and vibrating sample magnetometry revealed that the as-produced bio-crudes are free of iron species, which accumulate in the generated bio-chars. Our findings also indicate that the energy recovery values via the HTL process are sensitive to the catalyst loading, with a threshold loading of 1.25 wt%. GC-MS studies show that the UNCFO not only influences the chemical nature of the resulting bio-crudes and bio-chars, but also the amount of fixed carbons in the solid residues. The detailed molecular characterization of the bio-crudes and bio-chars catalyzed by UNCFO represents the first systematic study reported using UFMA. This study brings forth new avenues to advance the highly-pure bio-crude production employing active, heterogeneous catalyst materials that are recoverable and recyclable for continuous thermochemical reactions.

Graphical abstract: Catalytic effect of ultrananocrystalline Fe3O4 on algal bio-crude production via HTL process

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Supplementary files

Article information

02 Jul 2015
30 Sep 2015
First published
05 Oct 2015

This article is Open Access

Nanoscale, 2015,7, 17664-17671
Article type
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Catalytic effect of ultrananocrystalline Fe3O4 on algal bio-crude production via HTL process

A. Rojas-Pérez, D. Diaz-Diestra, C. B. Frias-Flores, J. Beltran-Huarac, K. C. Das, B. R. Weiner, G. Morell and L. M. Díaz-Vázquez, Nanoscale, 2015, 7, 17664 DOI: 10.1039/C5NR04404A

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