Large-area synthesis of monolayered MoS2(1−x)Se2x with a tunable band gap and its enhanced electrochemical catalytic activity

Abstract

“Band gap engineering” in two-dimensional (2D) materials plays an important role in tailoring their physical and chemical properties. The tuning of the band gap is typically achieved by controlling the composition of the semiconductor alloys. However, large-area preparation of 2D alloys remains a major challenge. Here, we report the large-area synthesis of high-quality monolayered MoS_2(1−x)Se_2x with a size coverage of hundreds of microns using a chemical vapor deposition method. The photoluminescence (PL) spectroscopy results confirm the tunable band gap in MoS_2(1−x)Se_2x, which is modulated by varying the Se content. Atomic-scale analysis was performed and the chemical composition was characterized using high-resolution scanning transmission electron microscopy and X-ray photoemission spectroscopy. With the introduction of Se into monolayered MoS₂, it leads to enhanced catalytic activity in an electrochemical reaction for hydrogen generation, compared to monolayered MoS₂ and MoSe₂. It is promising as a potential alternative to expensive noble metals.