Issue 14, 2020

Synthesis by partial oxygenation of graphite-like carbon nitride (OCN) decorated with oleic diethanolamide borate (ODAB) for oil-based lubricant additives and its tribological properties

Abstract

Graphite-like carbon nitride (OCN) synthesized by partial oxygenation was decorated with lipophilic oleic diethanolamide borate (ODAB) groups via a reflux reaction. The as-modified ODAB-OCN nanosheets could achieve a high degree of dispersion in paraffin oil due to the intercalation of oil-friendly ODAB groups between the nanosheet layers. Notably, the results of the friction experiments revealed that ODAB-OCN, a lubricant additive, possessed excellent tribological properties. Unlike the results for pure oil, the average friction coefficient and wear rate for 0.20 wt% ODAB-OCN included in the oil decreased by 22.7% and 90.8%, respectively. This work will be of great significance for the application of graphite-like carbon nitride (g-C3N4) as an oil-based lubricant additive.

Graphical abstract: Synthesis by partial oxygenation of graphite-like carbon nitride (OCN) decorated with oleic diethanolamide borate (ODAB) for oil-based lubricant additives and its tribological properties

Article information

Article type
Paper
Submitted
11 Feb 2020
Accepted
28 Feb 2020
First published
02 Mar 2020

New J. Chem., 2020,44, 5377-5385

Synthesis by partial oxygenation of graphite-like carbon nitride (OCN) decorated with oleic diethanolamide borate (ODAB) for oil-based lubricant additives and its tribological properties

Z. He, C. Min, Y. Yang, K. Zhang, C. Dong, Y. Zhou and W. Shen, New J. Chem., 2020, 44, 5377 DOI: 10.1039/D0NJ00726A

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