Issue 35, 2019

A fully fused non-fullerene acceptor containing angular-shaped S,N-heteroacene and perylene diimide for additive-free organic solar cells

Abstract

Constructing fused perylene diimide (PDI) dimers with heteroaromatic bridges toward non-fullerene acceptors (NFAs) has become an efficient strategy to achieve high performance organic solar cells (OSCs). Here, FDTC-PDI containing fully fused two PDIs with one central unit of angular-shaped S,N-heteroacene was developed and explored as a novel NFA for OSCs. The molecular geometry, optical spectra, energy levels, charge carrier mobilities and the morphology discrepancies as well as the corresponding photovoltaic performance of FDTC-PDI and its non-fused precursor, DTC-PDI, were investigated and compared. Theoretical calculations reveal that FDTC-PDI has a better planar molecular conformation and more effective conjugated length than DTC-PDI. As a consequence, by blending FDTC-PDI with PTB7-Th as the electron acceptor and the electron donor material, respectively, the inverted solar cells exhibited an encouraging PCE of 4.78% along with a Jsc of 11.72 mA cm−2, a Voc of 0.96 V and a FF of 42.5%, which were superior to those of its counterpart DTC-PDI (2.68%). These results are associated with the higher molar extinction coefficient, more balanced carrier mobility and better morphology of FDTC-PDI as well as its high-lying LUMO energy level. Note that no solvent additive was used in the process of device optimizations, thus simplifying the device fabrication, and improving the stability and reproducibility of the photovoltaic devices. We also prospect much broader application of the angular-shaped S,N-heteroacene with rigidity and planarity as a promising building block for fully fused electron acceptors for accomplishing the challenges in organic solar cells.

Graphical abstract: A fully fused non-fullerene acceptor containing angular-shaped S,N-heteroacene and perylene diimide for additive-free organic solar cells

Supplementary files

Article information

Article type
Paper
Submitted
05 Jun 2019
Accepted
29 Jul 2019
First published
31 Jul 2019

New J. Chem., 2019,43, 13775-13782

A fully fused non-fullerene acceptor containing angular-shaped S,N-heteroacene and perylene diimide for additive-free organic solar cells

Z. Li, J. Wang, H. Huang, Y. Liu, Y. Yun, Z. Cheng, S. Liu, Z. Ding, B. Zhao and W. Huang, New J. Chem., 2019, 43, 13775 DOI: 10.1039/C9NJ02918D

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