Issue 21, 2019
From the journal:

New Journal of Chemistry

Self-sorting assembly of a calixarene/crown ether polypseudorotaxane gated by ion-pairing†

Nadia Manganaro,‡a   Ilenia Pisagatti, ORCID logo *a   Anna Notti, ORCID logo a   Melchiorre F. Parisi ORCID logo a  and  Giuseppe Gattuso ORCID logo *a  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, Università di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina, Italy
E-mail: ipisagatti@unime.it, ggattuso@unime.it

Abstract

A calix[5]arene monomer bearing two different ammonium sites assembles into a supramolecular polymer that self-sorts into a polypseudorotaxane upon addition of dibenzo-24-crown-8, but only in the presence of superweak counterions.

Graphical abstract: Self-sorting assembly of a calixarene/crown ether polypseudorotaxane gated by ion-pairing

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Article information

DOI
https://doi.org/10.1039/C9NJ01583C
Article type
Letter
Submitted
27 Mar 2019
Accepted
07 May 2019
First published
08 May 2019

New J. Chem., 2019,43, 7936-7940

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Self-sorting assembly of a calixarene/crown ether polypseudorotaxane gated by ion-pairing

N. Manganaro, I. Pisagatti, A. Notti, M. F. Parisi and G. Gattuso, New J. Chem., 2019, 43, 7936 DOI: 10.1039/C9NJ01583C

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