Issue 23, 2018

Silver-catalyzed ring-opening [3+2] annulation of cyclopropenones with amides

Abstract

A ring-opening [3+2] annulation reaction between cyclopropenones and amides was developed to produce 5-amino-2-furanones. Insertion of the carbonyl group of an amide to the C–C single bond of a cyclopropenone occurred efficiently in the presence of a catalytic amount of silver(I) triflate.

Graphical abstract: Silver-catalyzed ring-opening [3+2] annulation of cyclopropenones with amides

Supplementary files

Article information

Article type
Paper
Submitted
09 Sep 2018
Accepted
29 Oct 2018
First published
30 Oct 2018

New J. Chem., 2018,42, 19178-19182

Silver-catalyzed ring-opening [3+2] annulation of cyclopropenones with amides

T. Matsuda, Y. Tabata and H. Suzuki, New J. Chem., 2018, 42, 19178 DOI: 10.1039/C8NJ04579H

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