The first heterocubane cluster with a [W3GaS4] core†
Abstract
Paramagnetic cuboidal cluster [W3(GaBr)0.81(μ3-S)4(dppe)3Br3] was synthesized by treatment of the electron precise [W3(μ3-S)(μ-S)3(dppe)3Br3]Br with [Ga(η5-C5Me5)]6 and studied by EPR spectroscopy and magnetic measurements.