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Issue 13, 2018
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Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens

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Abstract

The reactivity of the 2-arylselanyl pyridine derivatives L1–L4 towards dihalogens X2 (X = I, Br) and interhalogens IX (X = Cl, Br) was studied in CHCl3 or CH3CN. The solid products obtained were structurally characterized and their nature points out the preference for CT spoke adducts and for seesaw insertion adducts to be formed at the N-donor and Se-donor site, respectively. DFT calculations were performed to provide a rationale for the structural diversity observed in the products obtained.

Graphical abstract: Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens

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Publication details

The article was received on 28 Jan 2018, accepted on 12 Mar 2018 and first published on 12 Mar 2018


Article type: Paper
DOI: 10.1039/C8NJ00495A
Citation: New J. Chem., 2018,42, 10592-10602

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    Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens

    R. Montis, M. Arca, M. C. Aragoni, A. J. Blake, C. Castellano, F. Demartin, F. Isaia, V. Lippolis, A. Pintus, E. J. Lenardão, G. Perin, A. E. O'Connor and S. Thurow, New J. Chem., 2018, 42, 10592
    DOI: 10.1039/C8NJ00495A

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