Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 13, 2018
Previous Article Next Article

Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens

Author affiliations

Abstract

The reactivity of the 2-arylselanyl pyridine derivatives L1–L4 towards dihalogens X2 (X = I, Br) and interhalogens IX (X = Cl, Br) was studied in CHCl3 or CH3CN. The solid products obtained were structurally characterized and their nature points out the preference for CT spoke adducts and for seesaw insertion adducts to be formed at the N-donor and Se-donor site, respectively. DFT calculations were performed to provide a rationale for the structural diversity observed in the products obtained.

Graphical abstract: Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens

Back to tab navigation

Supplementary files

Article information


Submitted
28 Jan 2018
Accepted
12 Mar 2018
First published
12 Mar 2018

New J. Chem., 2018,42, 10592-10602
Article type
Paper

Structural diversity in the products formed by the reactions of 2-arylselanyl pyridine derivatives and dihalogens

R. Montis, M. Arca, M. C. Aragoni, A. J. Blake, C. Castellano, F. Demartin, F. Isaia, V. Lippolis, A. Pintus, E. J. Lenardão, G. Perin, A. E. O'Connor and S. Thurow, New J. Chem., 2018, 42, 10592
DOI: 10.1039/C8NJ00495A

Social activity

Search articles by author

Spotlight

Advertisements