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Issue 10, 2018
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Complexes of guest–host type between C60 and group 9 metalloporphyrins

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Abstract

Half-sandwich iridium(III) and cobalt(III) porphyrin–C60 co-crystals, C60·IrIII(ttp)Ph and C60·CoIII(ttp)Ph/C7H8, and triangular-sandwich C60·3IrIII(ttp)Ph, where ttp = tetra-p-tolylporphyrinato dianion, were synthesized. These complexes were structurally characterized by single crystal X-ray crystallography and featured C60 locations near the metal atoms. The dynamic behaviour between IrIII(ttp)Ph and C60 in solution was examined by NMR spectroscopy.

Graphical abstract: Complexes of guest–host type between C60 and group 9 metalloporphyrins

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Supplementary files

Article information


Submitted
22 Dec 2017
Accepted
05 Feb 2018
First published
05 Feb 2018

New J. Chem., 2018,42, 7599-7602
Article type
Letter

Complexes of guest–host type between C60 and group 9 metalloporphyrins

C. T. To and K. S. Chan, New J. Chem., 2018, 42, 7599
DOI: 10.1039/C7NJ05081J

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