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Issue 3, 2018
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Synthesis of a heterogeneous Cu(OAc)2-anchored SBA-15 catalyst and its application in the CuAAC reaction

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Abstract

A novel dinuclear Cu(OAc)2-anchored SBA-15 catalyst was synthesized by simple proton exchange of a carboxyl functionalized mesoporous SBA-15 silica with Cu(OAc)2 in water. XAFS and EPR spectra were utilized to probe its structure. Such a Cu(II) solid material exhibited excellent catalytic activity for the azide–alkyne cycloaddition reaction in water without addition of either reductant or base.

Graphical abstract: Synthesis of a heterogeneous Cu(OAc)2-anchored SBA-15 catalyst and its application in the CuAAC reaction

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Article information


Submitted
19 Nov 2017
Accepted
08 Jan 2018
First published
10 Jan 2018

New J. Chem., 2018,42, 1612-1616
Article type
Letter

Synthesis of a heterogeneous Cu(OAc)2-anchored SBA-15 catalyst and its application in the CuAAC reaction

N. Sun, Z. Yu, H. Yi, X. Zhu, L. Jin, B. Hu, Z. Shen and X. Hu, New J. Chem., 2018, 42, 1612
DOI: 10.1039/C7NJ04495J

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