Issue 14, 2017
From the journal:

New Journal of Chemistry

Novel imine-linked porphyrin covalent organic frameworks with good adsorption removing properties of RhB†

Yuxia Hou,ab   Xiaomei Zhang,c   Chiming Wang,a   Dongdong Qi,a   Yongqing Gu,b   Ziqian Wangd  and  Jianzhuang Jiang ORCID logo *a  

* Corresponding authors

a Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing, China
E-mail: jianzhuang@ustb.edu.cn
Fax: +86 10-6233-2592

b Department of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, China

c Department of Chemistry and Chemical Engineering, Shandong Universit, Jinan, China

d The High School Affiliated To China University of Geosciences, Beijing, China

Abstract

A new imine-linked porphyrin covalent organic framework (COF) CuP-DMNDA-COF with a large surface area was constructed from the condensation between 5,10,15,20-tetra(p-amino-phenyl)porphyrinatocopper(II) (CuTAPP) and 2,6-dimethoxynaphthalene-1,5-dicarbaldehyde (DMNDA) under solvothermal conditions. Simple treatment of CuP-DMNDA-COF with iron(III) in acetone led to the formation of the Fe-coordinated COF material CuP-DMNDA-COF/Fe, which exhibits superior adsorption performance for Rhodamine B (RhB) with easy recyclability and sustainability, indicating its good application potential for wastewater treatment.

Graphical abstract: Novel imine-linked porphyrin covalent organic frameworks with good adsorption removing properties of RhB

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Article information

DOI
https://doi.org/10.1039/C7NJ00424A
Article type
Paper
Submitted
05 Feb 2017
Accepted
27 May 2017
First published
29 May 2017

New J. Chem., 2017,41, 6145-6151

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Novel imine-linked porphyrin covalent organic frameworks with good adsorption removing properties of RhB

Y. Hou, X. Zhang, C. Wang, D. Qi, Y. Gu, Z. Wang and J. Jiang, New J. Chem., 2017, 41, 6145 DOI: 10.1039/C7NJ00424A

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