Issue 2, 2017
From the journal:

New Journal of Chemistry

Palladium/copper-catalyzed arylation of alkenes with N′-acyl arylhydrazines†

Ji-Quan Zhang,‡*a   Jun Cao,‡a   Wei Li,a   Shu-Min Li,a   Yong-Kang Li,b   Jian-Ta Wanga  and  Lei Tang*a  

* Corresponding authors

a College of Pharmacy, Guizhou Medical University, Guiyang 550004, P. R. China
E-mail: zjq_cn@gmc.edu.cn, tlei1974@hotmail.com

b Guiyang No.1 Middle School, Guiyang 550081, P. R. China

Abstract

A novel ligand-free palladium/copper-catalyzed Heck-type coupling reaction of alkenes and N′-acyl arylhydrazines has been developed by using air as the terminal oxidant. This protocol features wide functional group tolerance and produces highly chemoselective and regioselective products with good to excellent yields.

Graphical abstract: Palladium/copper-catalyzed arylation of alkenes with N′-acyl arylhydrazines

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Article information

DOI
https://doi.org/10.1039/C6NJ03718F
Article type
Letter
Submitted
29 Nov 2016
Accepted
12 Dec 2016
First published
12 Dec 2016

New J. Chem., 2017,41, 437-441

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Palladium/copper-catalyzed arylation of alkenes with N′-acyl arylhydrazines

J. Zhang, J. Cao, W. Li, S. Li, Y. Li, J. Wang and L. Tang, New J. Chem., 2017, 41, 437 DOI: 10.1039/C6NJ03718F

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