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Issue 8, 2016
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Organocatalytic 1,3-dipolar [3+3] cycloaddition reaction of 1,2-cyclohexanedione with azides: direct access to highly substituted 1,2,3-triazoles

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Abstract

Enamine-mediated 1,3-dipolar [3+3] cycloaddition reactions of 1,2-cyclohexanedione with azides have been developed. This strategy could generate highly substituted 1,2,3-triazoles in high yields and high levels of regioselectivities. It has been demonstrated that various types of products could be obtained using different organocatalysts and substrates.

Graphical abstract: Organocatalytic 1,3-dipolar [3+3] cycloaddition reaction of 1,2-cyclohexanedione with azides: direct access to highly substituted 1,2,3-triazoles

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Article information


Submitted
08 Apr 2016
Accepted
08 Jun 2016
First published
09 Jun 2016

New J. Chem., 2016,40, 6559-6563
Article type
Letter

Organocatalytic 1,3-dipolar [3+3] cycloaddition reaction of 1,2-cyclohexanedione with azides: direct access to highly substituted 1,2,3-triazoles

X. Xu, Z. Shi and W. Li, New J. Chem., 2016, 40, 6559
DOI: 10.1039/C6NJ01083K

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