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Issue 1, 2015
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O-Arylation with nitroarenes: metal-catalyzed and metal-free methodologies

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Abstract

In this article, we focus on the introduction of nitroarene as an alternative electrophile for Caryl–O cross-coupling chemistry. In polar aprotic solvents and in the presence of a base at elevated temperature nitroarene undergoes cross-coupling with arylboronic acids or phenols under metal or metal-free reaction conditions. Compared to the conventional aryl halides, nitroarene provides highly attractive and environmentally friendly options for the synthesis of diaryl ether derivatives.

Graphical abstract: O-Arylation with nitroarenes: metal-catalyzed and metal-free methodologies

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Publication details

The article was received on 04 Aug 2014, accepted on 22 Sep 2014 and first published on 23 Sep 2014


Article type: Focus
DOI: 10.1039/C4NJ01293C
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New J. Chem., 2015,39, 31-37

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    O-Arylation with nitroarenes: metal-catalyzed and metal-free methodologies

    M. Mondal, S. K. Bharadwaj and U. Bora, New J. Chem., 2015, 39, 31
    DOI: 10.1039/C4NJ01293C

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