A donor–acceptor–donor (D–A–D) molecule based on 3-alkoxy-4-cyanothiophene and dithienopyrrole units as active material for organic solar cells

Abstract

A symmetrical donor–acceptor–donor D–A–D system built by connecting two dithienopyrrole donor blocks to a central electron acceptor obtained by dimerization of 3-alkoxy-4-cyano-thiophene has been synthesized and characterized. The compound combines a high photoluminescence efficiency with a broad absorption spectrum in the solid state and a band gap of 1.70 eV. A preliminary evaluation of the potentialities of this type of compound as donor material in bulk heterojunction solar cells using PC₆₁BM as electron acceptor is presented.