Issue 11, 2012
From the journal:

New Journal of Chemistry

Nickel phosphate molecular sieves VSB-5 as heterogeneous catalysts for synthesis of monosaccharides from formaldehyde and dihydroxyacetone

Irina V. Delidovich,a   Maria N. Timofeeva,*ab   Alexander Yu. Orlov,ac   Valentina N. Panchenko,a   Zubair Hasan,d   Sung Hwa Jhung,*d   Oxana P. Tarana  and  Valentin N. Parmonac  

* Corresponding authors

a Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, Novosibirsk, Russian Federation
E-mail: timofeeva@catalysis.ru
Fax: +7 383 330 8056
Tel: +7 383 330 7284

b Novosibirsk State Technichal University, 630092, Pr. K. Marksa 20, Novosibirsk, Russia

c Novosibirsk State University, 630090, st. Pirogova 2, Novosibirsk, Russia

d Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu, Republic of Korea
E-mail: sung@knu.ac.kr
Fax: +82 53 950 6330
Tel: +82 53 950 5341

Abstract

Condensation of dihydroxyacetone with formaldehyde was found to be effectively catalyzed by nickel phosphate molecular sieves (VSB-5 and Fe–VSB-5) in neutral aqueous medium. In the presence of VSB-5 the main products are erythrulose and 3-pentulose, while Fe–VSB-5 favours the formation of only erythrulose.

Graphical abstract: Nickel phosphate molecular sieves VSB-5 as heterogeneous catalysts for synthesis of monosaccharides from formaldehyde and dihydroxyacetone

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Article information

DOI
https://doi.org/10.1039/C2NJ40363C
Article type
Letter
Submitted
07 May 2012
Accepted
04 Sep 2012
First published
19 Sep 2012

New J. Chem., 2012,36, 2201-2204

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Nickel phosphate molecular sieves VSB-5 as heterogeneous catalysts for synthesis of monosaccharides from formaldehyde and dihydroxyacetone

I. V. Delidovich, M. N. Timofeeva, A. Yu. Orlov, V. N. Panchenko, Z. Hasan, S. H. Jhung, O. P. Taran and V. N. Parmon, New J. Chem., 2012, 36, 2201 DOI: 10.1039/C2NJ40363C

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