A water-soluble fluoroionophore: p-(4-sulfonatophenyl)calix[8]arene†
Abstract
The conformational flexibility of water-soluble p-(4-sulfonatophenyl)calix[8]arene leads to pH dependent autofluorescence. Solution-based and solid-state techniques are consistent with the spontaneous formation of intra-molecular excimers upon solvation, with molecular simulations revealing that this occurs through π-stacking. Time-based fluorescence intensity studies provide insight into the solution dynamics, and solvated shelf-life, to significantly enhance the analytical protocol. Conductivity techniques support the formation of micelles, with no evidence for a direct link between higher-order structures and autofluorescence. Disruption of this excimer by