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Issue 11, 2010
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Synthesis, crystal structures, luminescent and thermal properties of two new metal–organic coordination polymers based on zinc(II) carboxylates

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Abstract

Two new metal–organic coordination polymers, [NH2(CH3)2]2[Zn3(bdc)4]·DMF·H2O (1) (H2bdc = 1,4-benzenedicarboxylic acid) and [NH2(CH3)2]2[Zn3(bpdc)4]·5DMF (2) (H2bpdc = 4,4′-biphenyldicarboxylic acid), were synthesized by heating a DMF solution of Zn(NO3)2·6H2O, [NH2(CH3)2]Cl and organic carboxylic acids. Single-crystal X-ray structure analysis reveals that these compounds have 3D anionic framework structures built from zinc(II) carboxylate layers linked by carboxylate anions. Compounds 1 and 2 were characterized by IR, TGA and XRPD, and their luminescent properties were also investigated.

Graphical abstract: Synthesis, crystal structures, luminescent and thermal properties of two new metal–organic coordination polymers based on zinc(ii) carboxylates

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Publication details

The article was received on 15 Mar 2010, accepted on 10 Jun 2010 and first published on 07 Jul 2010


Article type: Paper
DOI: 10.1039/C0NJ00196A
New J. Chem., 2010,34, 2445-2450

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    Synthesis, crystal structures, luminescent and thermal properties of two new metal–organic coordination polymers based on zinc(II) carboxylates

    S. A. Sapchenko, D. N. Dybtsev, D. G. Samsonenko and V. P. Fedin, New J. Chem., 2010, 34, 2445
    DOI: 10.1039/C0NJ00196A

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