Issue 1, 2010
From the journal:

New Journal of Chemistry

Synthesis and use of a surface-active initiator in emulsion polymerization under AGET and ARGET ATRP conditions†

Chuanjie Cheng,a   Jinbing Shu,a   Shanshan Gong,a   Liang Shen,*a   Yongluo Qiaoa  and  Changqing Fua  

* Corresponding authors

a Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science & Technology Normal University, Fenglin Street Nanchang, Jiangxi 330013, PR China
E-mail: shenliang00@tsinghua.org.cn
Fax: 86-791-3823357
Tel: 86-791-3805183

Abstract

A novel surface-active ATRP initiator disodium 4-(10-(2-bromo-2-methylpropanoyloxy)decyloxy)-4-oxo-2-sulfonatobutanoate (1a) has been designed and synthesized efficiently in three steps. The controlled radical emulsion polymerizations of methyl methacrylate (MMA) were realized in one step without any added surfactant under AGET and ARGET ATRP conditions, in which the initiator 1 functioned as both an ATRP initiator and a latex stabilizer.

Graphical abstract: Synthesis and use of a surface-active initiator in emulsion polymerization under AGET and ARGET ATRP conditions

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Article information

DOI
https://doi.org/10.1039/B9NJ00307J
Article type
Paper
Submitted
03 Jul 2009
Accepted
28 Sep 2009
First published
05 Nov 2009

New J. Chem., 2010,34, 163-170

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Synthesis and use of a surface-active initiator in emulsion polymerization under AGET and ARGET ATRP conditions

C. Cheng, J. Shu, S. Gong, L. Shen, Y. Qiao and C. Fu, New J. Chem., 2010, 34, 163 DOI: 10.1039/B9NJ00307J

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