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Issue 4, 2009
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The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions

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Abstract

Complexes of the type (L–L)MoO(O2)2 heterogenized on phenylene-bridged mesoporous organosilicas show a 10-fold increase in catalytic activity and a high stability in liquid phase epoxidation reactions, with H2O2 as the oxidant, compared to the corresponding MCM-41-derived systems.

Graphical abstract: The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions

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Publication details

The article was received on 26 Jan 2009, accepted on 09 Feb 2009 and first published on 17 Feb 2009


Article type: Letter
DOI: 10.1039/B901600G
New J. Chem., 2009,33, 717-719

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    The enhanced catalytic activity and stability of oxodiperoxomolybdenum-modified mesoporous organosilicas in selective epoxidation reactions

    S. P. Shylesh, M. Jia, A. Seifert, S. Adappa, S. Ernst and W. R. Thiel, New J. Chem., 2009, 33, 717
    DOI: 10.1039/B901600G

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