Issue 6, 2006
From the journal:

New Journal of Chemistry

Non-covalent interactions between anions and a cationic rhenium diamine complex: structural characterization of the supramolecular adducts

Sonia Nieto,a   Julio Pérez,*a   Lucía Riera,a   Víctor Rieraa  and  Daniel Miguelb  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica-IUQOEM, Facultad de Química, Universidad de Oviedo-CSIC, Oviedo, Spain
E-mail: japm@uniovi.es
Fax: +34 98510 3446
Tel: +34 98510 3465

b Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Valladolid, Spain

Abstract

The behavior of the new cationic complex [Re(CNtBu)(CO)3(N–N)]+ (N–N = 1,2-phenylenediamine) toward several inorganic anions (X−) has been investigated both in solution (by 1H NMR) and in the solid state (by X-ray diffraction), and the results show the formation of supramolecular adducts featuring N–H⋯X hydrogen bonds.

Graphical abstract: Non-covalent interactions between anions and a cationic rhenium diamine complex: structural characterization of the supramolecular adducts

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Article information

DOI
https://doi.org/10.1039/B602907H
Article type
Letter
Submitted
01 Mar 2006
Accepted
13 Apr 2006
First published
27 Apr 2006

New J. Chem., 2006,30, 838-841

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Non-covalent interactions between anions and a cationic rhenium diamine complex: structural characterization of the supramolecular adducts

S. Nieto, J. Pérez, L. Riera, V. Riera and D. Miguel, New J. Chem., 2006, 30, 838 DOI: 10.1039/B602907H

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