Issue 2, 2003
From the journal:

New Journal of Chemistry

Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n

Rui-Biao Fu,a   Sheng-Min Hu,a   Zhi-Yong Fu,a   Jian-Jun Zhanga  and  Xin-Tao Wu*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian, P.R. China
E-mail: wxt@ms.fjirsm.ac.cn
Fax: +86 591 371 4946
Tel: +86 591 379 2837

Abstract

A helical chain of [Co(1,10-phen)2(V2O4)(O3PCH2CH2CH2PO3)]n (1) and a stepped chain of [{Co(1,10-phen)2}2(V4O10)(O3PCH2CH2CH2CH2PO3)(2H2O)]n (2) have been synthesized under hydrothermal conditions using [Co(1,10-phen)2]2+ as the metal-organic subunit and organic diphosphonate ligands of different lengths.

Graphical abstract: Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B209564E
Article type
Letter
Submitted
30 Sep 2002
Accepted
21 Nov 2002
First published
12 Dec 2002

New J. Chem., 2003,27, 230-232

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Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)2(V2O4) (O3PCH2CH2CH2PO3)]n and [{Co(1,10-phen)2}2(V4O10) (O3PCH2CH2CH2CH2PO3)(2H2O)]n

R. Fu, S. Hu, Z. Fu, J. Zhang and X. Wu, New J. Chem., 2003, 27, 230 DOI: 10.1039/B209564E

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