Issue 1, 2003

Preservation of the cluster core upon formation of Ti3O(OPri)8(benzoate)2 from Ti3O(OR)10

Abstract

The cluster Ti3O(OPri)8(benzoate)2 is obtained upon reaction of Ti3O(OPri)10 or Ti3O(OPri)9(OMe) with benzoic acid. The remarkable feature of this substitution reaction is that the cluster structure is approximately preserved. Ti3O(OPri)8(benzoate)2 undergoes a dynamic exchange processes of the propoxy groups in solution.

Graphical abstract: Preservation of the cluster core upon formation of Ti3O(OPri)8(benzoate)2 from Ti3O(OR)10

Supplementary files

Article information

Article type
Letter
Submitted
22 Aug 2002
Accepted
25 Sep 2002
First published
14 Nov 2002

New J. Chem., 2003,27, 3-5

Preservation of the cluster core upon formation of Ti3O(OPri)8(benzoate)2 from Ti3O(OR)10

I. Mijatovic, G. Kickelbick, M. Puchberger and U. Schubert, New J. Chem., 2003, 27, 3 DOI: 10.1039/B208255A

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