Issue 11, 2002
From the journal:

New Journal of Chemistry

Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)

Sylvie L. Renard,a   Andreas Franken,a   Colin A. Kilner,a   John D. Kennedya  and  Malcolm A. Halcrow*a  

* Corresponding authors

a Department of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK
E-mail: M.A.Halcrow@chem.leeds.ac.uk

Abstract

The cations in [ZnCl(HpztBu)3]Y (Y− = [Co(C2B9H11)2]− or [1-Ph-closo-1-CB9H9]−) associate into dimers in the crystal, presenting a bowl-shaped face into which the carbaborane anions can pack. In contrast, the cations in [ZnCl(HpztBu)3][6,7,8,9,10-Br5-closo-1-CB9H5]·H2O associate with each other into a 1-D hydrogen-bonded polymer.

Graphical abstract: Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)

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Article information

DOI
https://doi.org/10.1039/B207966F
Article type
Paper
Submitted
12 Aug 2002
Accepted
24 Sep 2002
First published
15 Oct 2002

New J. Chem., 2002,26, 1634-1637

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Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)

S. L. Renard, A. Franken, C. A. Kilner, J. D. Kennedy and M. A. Halcrow, New J. Chem., 2002, 26, 1634 DOI: 10.1039/B207966F

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