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Issue 11, 2002
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Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)

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Abstract

The cations in [ZnCl(HpztBu)3]Y (Y = [Co(C2B9H11)2] or [1-Ph-closo-1-CB9H9]) associate into dimers in the crystal, presenting a bowl-shaped face into which the carbaborane anions can pack. In contrast, the cations in [ZnCl(HpztBu)3][6,7,8,9,10-Br5-closo-1-CB9H5]·H2O associate with each other into a 1-D hydrogen-bonded polymer.

Graphical abstract: Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)

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Publication details

The article was received on 12 Aug 2002, accepted on 24 Sep 2002 and first published on 15 Oct 2002


Article type: Paper
DOI: 10.1039/B207966F
New J. Chem., 2002,26, 1634-1637

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    Carbaborane salts of [ZnCl(HpztBu)3]+, a host for inorganic anions (HpztBu = 5-tert-butylpyrazole)

    S. L. Renard, A. Franken, C. A. Kilner, J. D. Kennedy and M. A. Halcrow, New J. Chem., 2002, 26, 1634
    DOI: 10.1039/B207966F

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