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Issue 9, 2019
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Reconfigurable assembly of charged polymer-modified Janus and non-Janus particles: from half-raspberries to colloidal clusters and chains

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Abstract

Understanding the dynamic and reversible assembly of colloids and particles into complex constructs, inspired by natural phenomena, is of fundamental significance for the fabrication of multi-scale responsive and reconfigurable materials. In this work, we investigate the pH-triggered and reconfigurable assembly of structures composed of binary mixtures of oppositely charged polyacrylic acid (PAA)-modified non-Janus and poly(2-dimethylamino)ethyl methacrylate (PDMAEMA)/poly(N-isopropylacrylamide) (PNIPAM)-modified Janus particles driven by electrostatic interactions. Three different target structures are visible both in dispersions and in dry state: half-raspberry structures, colloidal clusters and colloidal chains depending on the mass, numerical and particle size ratio. All formed structures are well-defined and stable in a certain pH range. Half-raspberry-like structures are obtained at pH 6 and numerical ratios NJP/PAA-HP of 1 : 500 (for 200-PAA-HP), 1 : 44 (for 450-PAA-HP) and 1 : 15 (for 650-PAA-HP), respectively, due to electrostatic interactions between the central JP and the excessive PAA-HP. Colloidal chains and cluster-like structures are generated at numerical ratios NJP/PAA-HP of 4 : 5 (for 200-PAA-HP), 4 : 3 (for 450-PAA-HP), and 4 : 1 (for 650-PAA-HP). Moreover, the smaller the size of a “connecting” PAA colloid, the larger is the average length of a colloidal chain. Depending on the particle size ratio SJP/PAA-HP, some of the observed structures can be disassembled on demand by changing the pH value either close to the IEP of the PDMAEMA (for half-raspberries) or PAA (for colloidal clusters and chains) and then reassembled into new stable structures many times. The obtained results open a pathway to pH-controlled reconfigurable assembly of a binary mixture composed of polymeric-modified non-Janus and Janus particles, which allow the reuse of particle building blocks.

Graphical abstract: Reconfigurable assembly of charged polymer-modified Janus and non-Janus particles: from half-raspberries to colloidal clusters and chains

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Supplementary files

Article information


Submitted
20 Aug 2019
Accepted
21 Aug 2019
First published
22 Aug 2019

This article is Open Access

Nanoscale Adv., 2019,1, 3715-3726
Article type
Paper

Reconfigurable assembly of charged polymer-modified Janus and non-Janus particles: from half-raspberries to colloidal clusters and chains

C. Marschelke, O. Diring and A. Synytska, Nanoscale Adv., 2019, 1, 3715
DOI: 10.1039/C9NA00522F

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

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    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
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    [Original citation] - Published by The Royal Society of Chemistry.

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