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Stereochemistry, like any other science, consists fully of previously 'impossible' things, the creation of which is carefully prepared by predecessors. What remains is only to see them, to realize them and to make them possible. Sometimes the whole life needed to do that, but more often it is even not enough.
Impossible things in stereochemistry
R. G. Kostyanovsky, Mendeleev Commun., 2004, 14, 229 DOI: 10.1070/MC2004v014n06ABEH002104
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