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Issue 3, 2003
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Generation of an optically active rhodium(III) complex by crystallization-induced spontaneous resolution of a racemic mixture

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Abstract

Racemic (π-pentamethylcyclopentadienyl)(2,2,2-trifluoro-1-phenylethyl diethylphosphinite)rhodium dichloride 2 was found to be a conglomerate, which undergoes spontaneous resolution during crystallization.

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Article information


Submitted
24 Apr 2003

Mendeleev Commun., 2003,13, 102-104
Article type
Communication

Generation of an optically active rhodium(III) complex by crystallization-induced spontaneous resolution of a racemic mixture

I. L. Odinets, O. I. Artyushin, E. V. Sharova, E. I. Goryunov, D. G. Golovanov, K. A. Lyssenko, P. V. Petrovskii and T. A. Mastryukova, Mendeleev Commun., 2003, 13, 102
DOI: 10.1070/MC2003v013n03ABEH001778

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