Issue 11, 2009
From the journal:

Molecular BioSystems

How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?†‡

Ashley N. Lamma  and  Shih-Yuan Liu*a  

* Corresponding authors

a Department of Chemistry, University of Oregon, Eugene
E-mail: lsy@uoregon.edu
Fax: +1 (541) 346-0487
Tel: +1 (541) 346-5573

Abstract

The stability of 1,2-dihydro-1,2-azaborines toward oxygen and water was investigated as a function of their ring substituents: while generally 1,2-dihydro-1,2-azaborines are compatible with water, their stability toward oxygen is dependent on the boron and the C(3) substituents, and we found that electron withdrawing groups enhanced the heterocycle’s ability to resist oxidative degradation.

Graphical abstract: How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?

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Article information

DOI
https://doi.org/10.1039/B904120F
Article type
Communication
Submitted
27 Feb 2009
Accepted
20 Jul 2009
First published
10 Aug 2009

Mol. BioSyst., 2009,5, 1303-1305

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How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?

A. N. Lamm and S. Liu, Mol. BioSyst., 2009, 5, 1303 DOI: 10.1039/B904120F

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