Functionalisation of MOF open metal sites with pendant amines for CO2 capture

Carmen Montoro; Elena García; Sofía Calero; María A. Pérez-Fernández; Antonio L. López; Elisa Barea; Jorge A. R. Navarro

doi:10.1039/C2JM16770K

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Functionalisation of MOF open metal sites with pendant amines for CO₂ capture†

Carmen Montoro,^a Elena García,^b Sofía Calero,^b María A. Pérez-Fernández,^c Antonio L. López,^c Elisa Barea*^a and Jorge A. R. Navarro*^a

Author affiliations

* Corresponding authors

^a Universidad de Granada, Departamento de Química Inorganica, 18071 Granada, Spain
E-mail: jarn@ugr.es
Fax: +34 958 248526
Tel: +34 958 248093

^b Departamento de Sistemas Físicos, Químicos y Naturales, Universidad Pablo de Olavide, 41013 Sevilla, Spain

^c R&D Department, CCS Technologies, Instalaciones Inabensa, S.A., CIL Torrecuéllar, Sevilla, Spain

Abstract

The present work deals with the study of the effect of functionalisation of open metal sites in [Cu₃(btc)₂] (btc = 1,3,5-benzenetricarboxylate) [HKUST-1] with bifunctional amines for CO₂ adsorption under dry and humid conditions.

This article is part of the themed collection: Integrating functionality into metal–organic frameworks

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Article information

DOI: https://doi.org/10.1039/C2JM16770K
Article type: Communication
Submitted: 22 Dec 2011
Accepted: 23 Mar 2012
First published: 10 Apr 2012

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J. Mater. Chem., 2012,22, 10155-10158

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Functionalisation of MOF open metal sites with pendant amines for CO₂ capture

C. Montoro, E. García, S. Calero, M. A. Pérez-Fernández, A. L. López, E. Barea and J. A. R. Navarro, J. Mater. Chem., 2012, 22, 10155 DOI: 10.1039/C2JM16770K

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Journal of Materials Chemistry