Issue 20, 2012

Kinetic hysteresis in gas adsorption behavior for a rigid MOF arising from zig-zag channel structures

Abstract

A new porous MOF, Zn(TBC)2·{guest}, is synthesized and studied by the single crystallography, N2 isothermal adsorption and GC separation of CO2 from air. This MOF shows large hysteresis on N2 adsorption at 77 K up to a P/Po of 0.9, which arises from the unique zig-zag channel structures of the framework. The MOF shows promising separation ability for CO2 from air.

Graphical abstract: Kinetic hysteresis in gas adsorption behavior for a rigid MOF arising from zig-zag channel structures

Supplementary files

Article information

Article type
Paper
Submitted
14 Nov 2011
Accepted
08 Feb 2012
First published
16 Mar 2012

J. Mater. Chem., 2012,22, 10166-10171

Kinetic hysteresis in gas adsorption behavior for a rigid MOF arising from zig-zag channel structures

Q. Wei, D. Yang, T. E. Larson, T. L. Kinnibrugh, R. Zou, N. J. Henson, T. Timofeeva, H. Xu, Y. Zhao and B. R. Mattes, J. Mater. Chem., 2012, 22, 10166 DOI: 10.1039/C2JM15860D

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