Issue 20, 2012

MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

Abstract

The adsorption/desorption of up to 0.75 g of water vapour per g of the porous MOFs 3D-{M3O(X)(H2O)2[btc]2·nH2O}, MIL-100 (M = Al, Fe; X = OH, F, btc = benzene-1,3,5-tricarboxylate, trimesate), occurs at small relative pressures of p/p0 < 0.4 and a comparatively small hysteresis. Together with very good cycle stability, these properties render both MIL-100(Al and Fe) very suitable candidates for thermally driven heat pumps or adsorption chillers.

Graphical abstract: MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

Supplementary files

Article information

Article type
Communication
Submitted
02 Nov 2011
Accepted
12 Dec 2011
First published
23 Dec 2011

J. Mater. Chem., 2012,22, 10148-10151

MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application

F. Jeremias, A. Khutia, S. K. Henninger and C. Janiak, J. Mater. Chem., 2012, 22, 10148 DOI: 10.1039/C2JM15615F

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