Preparation of inorganic–organic hybrid mesoporous material incorporating organoruthenium complexes (–[C6H4RuCp]PF6–) and its application as a heterogeneous catalyst

Takashi Kamegawa; Masakazu Saito; Tetsuji Watanabe; Kazuhiro Uchihara; Motoki Kondo; Masaya Matsuoka; Masakazu Anpo

doi:10.1039/C1JM12073E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Preparation of inorganic–organic hybrid mesoporous material incorporating organoruthenium complexes (–[C₆H₄RuCp]PF₆–) and its application as a heterogeneous catalyst†

Takashi Kamegawa,^a Masakazu Saito,^a Tetsuji Watanabe,^a Kazuhiro Uchihara,^a Motoki Kondo,^a Masaya Matsuoka*^a and Masakazu Anpo^a

Author affiliations

* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, Japan
E-mail: matsumac@chem.osakafu-u.ac.jp
Fax: +81-72-254-9910
Tel: +81-72-254-9288

Abstract

Inorganic–organic hybrid mesoporous material incorporating organoruthenium complexes within its organosilica frameworks (HMM–phRuCpPF₆) has been successfully prepared by a ligand exchange reaction. HMM–phRuCpPF₆ acts as a unique heterogeneous catalyst for hydrosilylation of 1-hexyne to produce α-vinylsilane at elevated temperatures.

Download options Please wait...

Supplementary files

Supplementary information PDF (430K)

Article information

DOI: https://doi.org/10.1039/C1JM12073E
Article type: Communication
Submitted: 10 May 2011
Accepted: 06 Jul 2011
First published: 21 Jul 2011

Download Citation

J. Mater. Chem., 2011,21, 12228-12231

Permissions

Request permissions

Preparation of inorganic–organic hybrid mesoporous material incorporating organoruthenium complexes (–[C₆H₄RuCp]PF₆–) and its application as a heterogeneous catalyst

T. Kamegawa, M. Saito, T. Watanabe, K. Uchihara, M. Kondo, M. Matsuoka and M. Anpo, J. Mater. Chem., 2011, 21, 12228 DOI: 10.1039/C1JM12073E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Fetching data from CrossRef.
This may take some time to load.

Journal of Materials Chemistry