Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D2h-hexakis-[60]fullerene adduct

Angy L. Ortiz; Luis Echegoyen

doi:10.1039/C0JM00754D

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Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D_2h-hexakis-[60]fullerene adduct†‡

Angy L. Ortiz^a and Luis Echegoyen*^a

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* Corresponding authors

^a Department of Chemistry, Clemson University, 219 Hunter Laboratories, Clemson, SC, USA
E-mail: luis@clemson.edu
Fax: (+) 864-656-6613

Abstract

An (e,e,e,e)-tetrakis-adduct of C₆₀fullerene with two pyridylpyrrolidino addends (trans-1 position relative to each other) and two (ethoxycarbonyl)methano addends (trans-1 position relative to each to other) compound 4, was obtained selectively by controlled potential electrolysis of the D_2h-hexakis-adduct 3.

This article is part of the themed collection: Celebrating the 70th birthday of Professor Fred Wudl

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Supplementary files

Maldi-TOF, ¹H-NMR, ¹³C-NMR, HMBC, HMQC, UV-vis spectra PDF (1011K)

Article information

DOI: https://doi.org/10.1039/C0JM00754D
Article type: Communication
Submitted: 18 Mar 2010
Accepted: 23 Apr 2010
First published: 21 May 2010

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J. Mater. Chem., 2011,21, 1362-1364

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Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D_2h-hexakis-[60]fullerene adduct

A. L. Ortiz and L. Echegoyen, J. Mater. Chem., 2011, 21, 1362 DOI: 10.1039/C0JM00754D

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Journal of Materials Chemistry