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Issue 5, 2011
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Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D2h-hexakis-[60]fullerene adduct

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Abstract

An (e,e,e,e)-tetrakis-adduct of C60fullerene with two pyridylpyrrolidino addends (trans-1 position relative to each other) and two (ethoxycarbonyl)methano addends (trans-1 position relative to each to other) compound 4, was obtained selectively by controlled potential electrolysis of the D2h-hexakis-adduct 3.

Graphical abstract: Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D2h-hexakis-[60]fullerene adduct

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Article information


Submitted
18 Mar 2010
Accepted
23 Apr 2010
First published
21 May 2010

J. Mater. Chem., 2011,21, 1362-1364
Article type
Communication

Unexpected and selective formation of an (e,e,e,e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D2h-hexakis-[60]fullerene adduct

A. L. Ortiz and L. Echegoyen, J. Mater. Chem., 2011, 21, 1362
DOI: 10.1039/C0JM00754D

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