Issue 33, 2009

Fabrication of ZnO/CdS core/shell nanowire arrays for efficient solar energy conversion

Abstract

ZnO/CdS core/shell nanowire heterostructure arrays are fabricated by a two-step chemical solution method for use in semiconductor-sensitized photoelectrochemical cells (PECs). The successive ion layer adsorption and reaction (SILAR) shows a remarkable controllability of CdS shell thickness, which affects visible-light absorption properties and PEC performances of the heterostructures. The cell has a high short-circuit photocurrent density of 7.23 mA/cm2 with a power conversion efficiency of 3.53% under AM 1.5G illumination at 100 mW/cm2. These results demonstrate that the ZnO/CdS core/shell heterostructure nanowire arrays can provide a facile and compatible frame for the potential applications in nanowire-based solar cells.

Graphical abstract: Fabrication of ZnO/CdS core/shell nanowire arrays for efficient solar energy conversion

Article information

Article type
Paper
Submitted
11 Mar 2009
Accepted
04 Jun 2009
First published
30 Jun 2009

J. Mater. Chem., 2009,19, 5945-5951

Fabrication of ZnO/CdS core/shell nanowire arrays for efficient solar energy conversion

Y. Tak, S. J. Hong, J. S. Lee and K. Yong, J. Mater. Chem., 2009, 19, 5945 DOI: 10.1039/B904993B

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