Hg2Ru2O7, a new pyrochlore showing a metal–insulator transition

Abstract

Hg₂Ru₂O₇ was prepared by reaction of HgO and RuO₂ at 400 °C under elevated oxygen pressure. According to a single crystal structure determination, the compound adopts the pyrochlore structure with a cubic lattice parameter of 10.2011(1) Å. From heat capacity measurements, a second order phase transition at 108 K was detected, consistent with a change from metallic to semiconducting behaviour as well as from paramagnetic to antiferromagnetic at lower temperatures. The behaviour is qualitatively very similar to that of Cd₂Os₂O₇ and Tl₂Ru₂O₇.