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Issue 35-36, 2005
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Poly[{(BuSn)12O14(OH)6}(AMPS)2] and poly[methyl acrylate-co-{(BuSn)12O14(OH)6}(AMPS)2]: hybrid polymers cross-linked through electrostatic interactions

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Abstract

A butyltin oxo-cluster, {(BuSn)12O14(OH)6}2+, functionalized through electrostatic interactions with two 2-acrylamido-2-methyl-1-propanesulfonate anions (AMPS), has been synthesized and characterized by single crystal X-ray diffraction and multinuclear (1H, 13C and 119Sn) NMR. Its polymerization or co-polymerization with methyl acrylate yield hybrid materials where the nanobuilding blocks are fully preserved and act as nano-fillers and cross-linking agents. According to the electrostatic nature of the cross-linking, these materials can yield gels or solutions depending on the solvent used to swell them.

Graphical abstract: Poly[{(BuSn)12O14(OH)6}(AMPS)2] and poly[methyl acrylate-co-{(BuSn)12O14(OH)6}(AMPS)2]: hybrid polymers cross-linked through electrostatic interactions

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Publication details

The article was received on 23 May 2005, accepted on 13 Jul 2005 and first published on 01 Aug 2005


Article type: Paper
DOI: 10.1039/B507214J
J. Mater. Chem., 2005,15, 3973-3978

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    Poly[{(BuSn)12O14(OH)6}(AMPS)2] and poly[methyl acrylate-co-{(BuSn)12O14(OH)6}(AMPS)2]: hybrid polymers cross-linked through electrostatic interactions

    F. Ribot, D. Veautier, S. J. Guillaudeu and T. Lalot, J. Mater. Chem., 2005, 15, 3973
    DOI: 10.1039/B507214J

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