Issue 9, 2002
From the journal:

Journal of Materials Chemistry

Nonlinear optical properties of novel carborane–ferrocene conjugated dyads. Electron-withdrawing characteristics of carboranes†

Norie Tsuboya,a   Mouad Lamrani,a   Ryo Hamasaki,a   Masateru Ito,a   Masaya Mitsuishi,b   Tokuji Miyashitab  and  Yoshinori Yamamoto*a  

* Corresponding authors

a Department of Chemistry, Graduate school of Science, Tohoku University, Sendai, Japan

b Institute for Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-2-1, Aoba-ku, Sendai, Japan

Abstract

The novel carborane–ferrocene conjugated dyads 1–3 and 6–8 were synthesized and their NLO properties were investigated. ortho-, meta-, and para-carboranes act as electron-withdrawing groups, and the para-carborane dyads 3 and 8 exhibited higher β values (hyperpolarizability) than the ortho- and meta-carborane analogues 1, 2, 6, 7.

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Article information

DOI
https://doi.org/10.1039/B202236B
Article type
Paper
Submitted
05 Mar 2002
Accepted
22 May 2002
First published
03 Jul 2002

J. Mater. Chem., 2002,12, 2701-2705

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Nonlinear optical properties of novel carborane–ferrocene conjugated dyads. Electron-withdrawing characteristics of carboranes

N. Tsuboya, M. Lamrani, R. Hamasaki, M. Ito, M. Mitsuishi, T. Miyashita and Y. Yamamoto, J. Mater. Chem., 2002, 12, 2701 DOI: 10.1039/B202236B

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