Issue 8, 2002
From the journal:

Journal of Materials Chemistry

Second-order non linear optical properties of nitrocalixarenes grafted to a sol-gel matrix

Mourad Regayeg,a   Alain Fort,b   Olivier Cregut,b   Anthony Coleman,c   Patrick Shahgaldian,c   Jacques Mugnier,d   Roger Lamartinea  and  Francis Vocanson*a  

* Corresponding authors

a SROMB, UMR 5078 CNRS, Université Lyon I, 43 boulevard du 11 novembre 1918, Villeurbanne Cédex, France
E-mail: f.vocanson@cdlyon.univ-lyon1.fr
Fax: 33 4 72 44 84 38
Tel: 33 4 72 44 80 14

b IPCMS-GONLO, UMR 7504 CNRS, 23 rue du Loess, Strasbourg Cedex, France

c IBCP, Université Lyon I, UMR 5086 CNRS, 7 passage du Vercors, Lyon Cédex 07, France

d LPCML, UMR 5620 CNRS, Université Lyon I, 43 boulevard du 11 novembre 1918, Villeurbanne Cédex, France

Abstract

5,11,17,23-Tetranitro-25-[4-[3-(trimethoxysilyl)propylthio]-butyloxy]-26,27,28-tripropyloxycalix[4]arene was prepared and fully characterized using 1H and 13C NMR. Elaboration of sol-gel matrix with this macrocycle and with tetranitrotetrapropoxycalix[4]arene from tetraethoxysilane was described. Thin films were obtained from these materials and studied using m-lines spectroscopy, AFM and NLO. Chemically grafted films exhibited high and stable NLO responses.

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Article information

DOI
https://doi.org/10.1039/B202131E
Article type
Paper
Submitted
28 Feb 2002
Accepted
26 Apr 2002
First published
13 Jun 2002

J. Mater. Chem., 2002,12, 2231-2236

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Second-order non linear optical properties of nitrocalixarenes grafted to a sol-gel matrix

M. Regayeg, A. Fort, O. Cregut, A. Coleman, P. Shahgaldian, J. Mugnier, R. Lamartine and F. Vocanson, J. Mater. Chem., 2002, 12, 2231 DOI: 10.1039/B202131E

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