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Issue 7, 2002
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Supramolecular assembly of a quasi-linear heterofullerene–porphyrin dyad

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Abstract

A novel supramolecular dyad (Zn-ttbpp–pyridine–C59N)—with a quasi-linear geometry—involving a heterofullerene acceptor and a zinc tetrakis(p-tert-butylphenyl)porphyrin (Zn-ttbpp) donor was assembled via axial coordination. Depending on the solvent either photoinduced singlet–singlet energy transfer or electron transfer was observed. The latter process takes place in o-dichlorobenzene as solvent and leads to the corresponding charge-separated state, that is, the π-radical anion of C59N and the π-radical cation of Zn-ttbpp.

Graphical abstract: Supramolecular assembly of a quasi-linear heterofullerene–porphyrin dyad

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Publication details

The article was received on 27 Feb 2002, accepted on 16 Apr 2002 and first published on 14 May 2002


Article type: Paper
DOI: 10.1039/B202060B
J. Mater. Chem., 2002,12, 2088-2094

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    Supramolecular assembly of a quasi-linear heterofullerene–porphyrin dyad

    F. Hauke, A. Swartz, D. M. Guldi and A. Hirsch, J. Mater. Chem., 2002, 12, 2088
    DOI: 10.1039/B202060B

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