Issue 12, 1999

Syntheses and structures of the open-framework phases (CH3NH3)3·Zn4O(AsO4)3 and (CH3NH3)3·Zn4O(PO4)3 related to the M3Zn4O(XO4)3·nH2O family

Abstract

The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)3·Zn4O(AsO4)3 and (CH3NH3)3·Zn4O(PO4)3 are reported. These compounds are built up from vertex-sharing three-dimensional “OZn4” + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)3·nH2O family of phases.

Supplementary files

Article information

Article type
Paper

J. Mater. Chem., 1999,9, 3087-3092

Syntheses and structures of the open-framework phases (CH3NH3)3·Zn4O(AsO4)3 and (CH3NH3)3·Zn4O(PO4)3 related to the M3Zn4O(XO4)3·nH2O family

W. T. A. Harrison, M. L. F. Phillips, A. V. Chavez and T. M. Nenoff, J. Mater. Chem., 1999, 9, 3087 DOI: 10.1039/A906009J

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