Issue 4, 1999

Preparation of α-Heteroatom Substituted Allylic Alcohols by Reaction of (E)-α-Selanylvinylzirconiums or (E)-α-Trimethylsilylvinylzirconiums with Aldehydes

Abstract

Both (E)-α-selanylvinylzirconium and (E)-α-trimethylsilylvinylzirconium complexes undergo AgClO4-catalyzed reactions with aldehydes to give α-seleno- or α-trimethylsilyl-substituted allylic alcohols, respectively.

Article information

Article type
Paper

J. Chem. Res. (S), 1999, 292-293

Preparation of α-Heteroatom Substituted Allylic Alcohols by Reaction of (E)-α-Selanylvinylzirconiums or (E)-α-Trimethylsilylvinylzirconiums with Aldehydes

X. Huang and A. Sun, J. Chem. Res. (S), 1999, 292 DOI: 10.1039/A900134D

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