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Issue 7, 2015
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Transient signal isotope analysis using multicollection of ion beams with Faraday cups equipped with 1012 Ω and 1011 Ω feedback resistors

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Abstract

To improve the precision of isotope analyses of low ion intensities using the Faraday detection system, amplifiers equipped with 1012 Ω resistors (hereafter 1012 Ω amplifiers) have been developed. While the behavior of these amplifiers for steady signals has been well investigated, there is no ample evidence regarding the use of 1012 Ω amplifiers for transient signal acquisition. In this work, we investigated the simultaneous use of amplifiers equipped with 1012 Ω and 1011 Ω resistors for transient signal acquisition. Using the equation describing the relationship between the input ion current and the output voltage in the amplifiers, we showed how the transient signal duration influences the accuracy of the isotope ratio measurements. In particular, lead transient signals were investigated using a Neptune Plus MC-ICPMS and 204Pb and 206Pb isotopes were measured using 1012 Ω and 1011 Ω amplifiers, respectively. The 204Pb/206Pb isotope ratio showed an important drift due to a large time lag between 1012 Ω and 1011 Ω amplifiers. The time lag was quantified (0.175(3) s) and the isotopic drift was corrected using a method of internal signal synchronization. The 204Pb/206Pb drift corrected data obtained from the 1012–1011 Ω amplifier configuration were compared to the data obtained from 1011–1011 Ω amplifiers. Our results point out that for low transient signal intensities (<10−13 A), the use of 1012–1011 Ω amplifiers is more beneficial in terms of isotope ratio uncertainty, repeatability and trueness, compared to the 1011–1011 Ω amplifier configuration.

Graphical abstract: Transient signal isotope analysis using multicollection of ion beams with Faraday cups equipped with 1012 Ω and 1011 Ω feedback resistors

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Article information


Submitted
20 Mar 2015
Accepted
21 Apr 2015
First published
21 Apr 2015

J. Anal. At. Spectrom., 2015,30, 1582-1589
Article type
Paper
Author version available

Transient signal isotope analysis using multicollection of ion beams with Faraday cups equipped with 1012 Ω and 1011 Ω feedback resistors

A. Gourgiotis, G. Manhès, P. Louvat, J. Moureau and J. Gaillardet, J. Anal. At. Spectrom., 2015, 30, 1582
DOI: 10.1039/C5JA00094G

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