Issue 6, 2003

Modelling the RF source in GDOES

Abstract

An equivalent model of an asymmetric radiofrequency (RF) powered glow discharge (GD) plasma is combined with an equivalent circuit of the stray cell capacitance, coaxial cable connection, matching box and power generator needed to drive it, to provide an electrical model of the impedance-matched RF source commonly used in GDOES. Component values in the matching circuit are determined in situ using procedures provided. The resulting model is then used to calculate plasma resistances based on the matching box settings. As a test of the model, these plasma resistances are then used as emission yield corrections in a multi-matrix calibration, and compared with the more familiar VDC corrections.

Article information

Article type
Paper
Submitted
29 Jan 2003
Accepted
05 Mar 2003
First published
04 Apr 2003

J. Anal. At. Spectrom., 2003,18, 656-664

Modelling the RF source in GDOES

R. Payling, O. Bonnot, E. Fretel, O. Rogerieux, M. Aeberhard, J. Michler, T. Nelis, U. Hansen, A. Hartmann, P. Belenguer and P. Guillot, J. Anal. At. Spectrom., 2003, 18, 656 DOI: 10.1039/B301156A

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